A A cubic B-spline collocation method for numerically solving fractional diffusion equations used in modelling dye-sensitized solar cells

Authors

DOI:

https://doi.org/10.21914/anziamproc.v62.15883

Keywords:

dye-sensitized solar cells, electron density, fractional diffusion, subdiffusion, titanium dioxide, mathematical modelling, finite difference methods, finite element methods

Abstract

As part of the third generation of solar cells, dye-sensitized solar cells (DSSCs) are a novel, cost effective solution to the renewable energy problem. Mathematical modelling provides unique insight into operating DSSCs efficiently, particularly in the role of diffusion in the nanoporous semiconductor of the device. A recently published fractional diffusion model explores the link between the electron density of DSSCs and the porosity of the semiconductor. In this article, we solve the fractional diffusion model numerically using cubic B-splines to discretise space and an implicit finite difference scheme to discretise time. We compute the error by a standard collocation method.

References

  • L. Andrade, J. Sousa, H. A. Ribeiro, and A. Mendes. Phenomenological modeling of dye-sensitized solar cells under transient conditions. In: Solar Energy 85.5 (2011), pp. 781–793. doi: 10.1016/j.solener.2011.01.014
  • J. A. Anta, F. Casanueva, and G. Oskam. A numerical model for charge transport and recombination in dye-sensitized solar cells. In: J. Phys. Chem. B 110.11 (2006), pp. 5372–5378. doi: 10.1021/jp056493h
  • K. D. Benkstein, N. Kopidakis, J. van de Lagemaat, and A. J. Frank. Influence of the percolation network geometry on electron transport in dye-sensitized titanium dioxide solar cells. In: J. Phys. Chem. B 107.31 (2003), pp. 7759–7767. doi: 10.1021/jp022681l on pp. C243, C250).
  • F. Cao, G. Oskam, G. J. Meyer, and P. C. Searson. Electron transport in porous nanocrystalline TiO2 photoelectrochemical cells. In: J. Phys. Chem. 100.42 (1996), pp. 17021–17027. doi: 10.1021/jp9616573
  • M. Caputo. Linear models of dissipation whose Q is almost frequency independent—II. In: Geophys. J. Int. 13.5 (1967), pp. 529–539. doi: 10.1111/j.1365-246X.1967.tb02303.x
  • T. S. El Danaf. Numerical solution for the linear time and space fractional diffusion equation. In: J. Vib. Control 21.9 (2015), pp. 1769–1777. doi: 10.1177/1077546313500687
  • A. Esen, Y. Ucar, N. Yagmurlu, and O. Tasbozan. A Galerkin finite element method to solve fractional diffusion and fractional diffusion-wave equations. In: Math. Mod. Anal. 18 (2013), pp. 260–273. doi: 10.3846/13926292.2013.783884
  • Y. Gacemi, A. Cheknane, and H. S. Hilal. Simulation and modelling of charge transport in dye-sensitized solar cells based on carbon nano-tube electrodes. In: Physica Scripta 87.3, 035703 (2013). doi: 10.1088/0031-8949/87/03/035703
  • R. Gómez and P. Salvador. Photovoltage dependence on film thickness and type of illumination in nanoporous thin flim electrodes according to a simple diffusion model. In: Solar Energy Mat. Solar Cells 88.4 (2005), pp. 377–388. doi: 10.1016/j.solmat.2004.11.008
  • B. I. Henry and S. L. Wearne. Fractional reaction-diffusion. In: Physica A 276 (2000), pp. 448–455. doi: 10.1016/S0378-4371(99)00469-0
  • N. Khalid, M. Abbas, M. K. Iqbal, and D. Baleanu. A numerical investigation of Caputo time fractional Allen–Cahn equation using refined cubic B-spline functions. In: Adv. Diff. Eq. 2020, 158 (2020). doi: 10.1186/s13662-020-02616-x
  • B. Maldon, B. P. Lamichhane, and N. Thamwattana. Numerical solutions for nonlinear partial differential equations arising from modelling dye-sensitized solar cells. In: Proceedings of the 18th Biennial Computational Techniques and Applications Conference, CTAC-2018. Ed. by B. Lamichhane, T. Tran, and J. Bunder. Vol. 60. ANZIAM J. 2019, pp. C231–C246. doi: 10.21914/anziamj.v60i0.14053
  • B. Maldon and N. Thamwattana. A fractional diffusion model for dye-sensitized solar cells. In: Molecules 25 (2020), pp. 2966–2975. doi: 10.3390/molecules25132966
  • B. Maldon and N. Thamwattana. An analytical solution for charge carrier densities in dye-sensitized solar cells. In: J. Photochem. Photobio. A 370 (2019), pp. 41–50. doi: 10.1016/j.jphotochem.2018.10.018
  • B. Maldon, N. Thamwattana, and M. Edwards. Exploring nonlinear diffusion equations for modelling dye-sensitized solar cells. In: Entropy 22 (2020), p. 248. doi: 10.3390/e22020248
  • R. C. Mittal and R. K. Jain. Cubic B-splines collocation method for solving nonlinear parabolic partial differential equations with Neumann boundary conditions. In: Comm. Nonlin. Sci. Numer. Sim. 17 (2012), pp. 4616–4625. doi: 10.1016/j.cnsns.2012.05.007 on pp. C245, C247).
  • J. Nelson. Continuous-time random-walk model of electron transport in nanocrystalline TiO2 electrodes. In: Phys. Rev. B 59.23 (1999), pp. 15374–15380. doi: 10.1103/PhysRevB.59.15374
  • M. Ni, M. K. H. Leung, D. Y. C. Leung, and K. Sumathy. An analytical study of the porosity effect on dye-sensitized solar cell performance. In: Solar Energy Mat. Solar Cells 90.9 (2006), pp. 1331–1344. doi: 10.1016/j.solmat.2005.08.006 on p. C250).
  • B. O’Regan and M. Grätzel. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. In: Nature 353 (1991), pp. 737–740. doi: 10.1038/353737a0
  • K. Oldham and J. Spanier. The fractional calculus: Theory and applications of differentiation and integration to arbitrary order. Vol. III. Elsevier, 1974. url: https://www.sciencedirect.com/bookseries/mathematics-inscience-and-engineering/vol/111/suppl/C
  • S. Södergren, A. Hagfeldt, J. Olsson, and S.-E. Lindquist. Theoretical models for the action spectrum and the current-voltage characteristics of microporous semiconductor films in electrochemical cells. In: J. Phys. Chem. 98 (1994), pp. 5552–5556. doi: 10.1021/J100072A023
  • W. K. Zahra and S. M. Elkholy. The use of cubic splines in the numerical solution of fractional differential equations. In: Int. J. Math. Math. Sci. 2012, 638026 (2012). doi: 10.1155/2012/638026

Author Biography

Benjamin James Maldon, School of Mathematical and Physical Sciences, University of Newcastle, NSW Australia

PhD Student

Published

2026-08-26

Issue

Section

Proceedings Computational Techniques and Applications Conference